This is known as the Goat Problem.
For simplicity we could set $r=1$ and $s=\pi r^2=\pi$, and assume the radius of $C_2$ is $R$. Using the formula in http://mathworld.wolfram.com/Circle-CircleIntersection.html:
\begin{align} \text{area of intersection} &= r^2\cos^{-1}\frac{d^2+r^2-R^2}{2dr} + R^2\cos^{-1}\frac{d^2+R^2-r^2}{2dR} \\ &\quad - \frac{\sqrt{(-d+r+R)(d+r-R)(d-r+R)(d+r+R)}}2 \end{align}
with $r=1$ and $d=1$ (since the center of $C_2$ is on the circumference of $C_1$) we get to solve
$$ R^2 \cos^{-1} \frac R2 + \cos^{-1}\left(1-\frac{R^2}2\right) - \frac{R\sqrt{4-R^2}}2 = \frac\pi2 $$
which doesn't have a closed-form solution. The numerical solution is $$ R=1.15872847301812151782823355653641924698\dotsc \times r.$$