Let $V$ be a finite dimensional real vector space, and $\langle-,-\rangle$ a symmetric, nondegenerate positive definite bilinear form on $V$. If $v \in V$, the Euclidean reflection about $v$ is defined to be the unique linear transformation $\phi: V \rightarrow V$ which sends $v$ to $-v$ and fixes pointwise all the elements in the orthogonal complement of $v$.
Let $G$ be a linear algebraic group, $T$ a maximal torus with character group $X$ and Weyl group $W$. View $X$ as an additive subgroup of $V = \mathbb{R} \otimes_{\mathbb{Z}} X$. Then $W$ extends to a group of automorphisms of $V$. Let $\langle - ,-\rangle$ be a bilinear form on $V$ as above which is fixed by the elements of the Weyl group.
Let $\alpha$ be a weight of $T$ such that $G_{\alpha} = Z_G((\textrm{Ker } \alpha)^0)$ is not solvable, so $W_{\alpha} = W(G_{\alpha},T)$ is a subgroup of $W$ with order $2$. Let $x \in N_{G_{\alpha}}(T)/Z_{G_{\alpha}}(T)$, and let $s_{\alpha}$ be the image of $x$ in $W$. Then $s_{\alpha}$ extends to an automorphism of $V$.
I'm trying to understand why $s_{\alpha}$ is the Euclidean reflection about $\alpha$. This is what Springer claims in Linear Algebraic Groups, (7.1.6). I just don't know how to use the condition that $(\alpha,\chi) = 0$, since I don't know much about the bilinear form. It is not difficult to see that $s_{\alpha}$ has to send $\alpha$ to $-\alpha$ (edit: not really, I would love for you to explain this as well), but I also need to show that if $\chi$ is a character of $T$ with $\langle \alpha, \chi \rangle = 0$, then $s_{\alpha}(\chi) = \chi$, or in other words, $\chi(y) = \chi(xyx^{-1})$ for all $y \in T$.