You are right, but let's think about why this is:
If $\sec \theta \leq -1$, then $-1 \leq \cos \theta < 0$, which implies Quadrant II or III. Thus, since the range of $\sec^{-1}$ is $[0, \pi]-\{\frac \pi 2\}$ (Quadrant I or II), we must have $\theta \in (\frac \pi 2, \pi]$ (Quadrant II)
Now, if $x \leq -1$, then $-1 < \frac{\sqrt{x^2-1}}{x}=\sin \alpha \leq 0$, which implies Quadrant III or Quadrant IV. Thus, since the range of $\sin^{-1}$ is $[-\frac \pi 2, \frac \pi 2]$ (Quadrant I or IV), we must have $\alpha \in (-\frac \pi 2, 0]$ (Quadrant IV).
Now, let's consider a few values of $x$:
$$x=-1 \implies \sin \alpha=0 \wedge \sec \theta=-1 \implies \alpha=0 \wedge \theta=\pi$$
$$x=-\frac{2}{\sqrt 3} \implies \sin \alpha=-\frac 1 2 \wedge \sec \theta=-\frac{2}{\sqrt 3} \implies \alpha=-\frac \pi 6 \wedge \theta=\frac{5\pi}{6}$$
As you see in our two examples, both $\alpha$ and $\theta$ have the same reference angles, but $\alpha$ is in Quadrant IV while $\theta$ is in Quadrant II. Thus, we just need to shift $\alpha$ into Quadrant II by rotating it $\pi$ radians, so we get $\alpha+\pi=\theta$, or:
$$\sin^{-1} \frac{\sqrt{x^2-1}}{x}+\pi=\sec^{-1}x$$