I think what you're saying is that if you take all the permutations in $S_4$ and multiply them together in whichever order, the result is never equal to your $a$.
Your basic plan is sound -- $a$ is indeed an odd permutation, and it will turn out that a product of all the permutations is even.
The product of all the permutations is even if and only if the total number of odd permutations in the product is even.
There are various ways of showing that. A quick and slick one is would be to know that exactly half of the elements of $S_n$ are odd (for $n\ge 2$), compute the size of $S_4$ and see that half of that number is even.
(Proof that exactly half of all permutations are odd: Fix some transposition -- say, your $a$ -- and then observe that if $\sigma$ is an even permutation, then $a\sigma$ is odd, and if $\tau$ is an even permutation, then $a\tau$ is an odd permutation such that $a(a\tau)=\tau$. So left multiplication by $a$ is a bijection between the even and the odd permutations, so there are equally many of them).