Using Ian's comment and Yves Daoust's answer, we get an initial value in the interval $(-1/5,3/5)$.
Since there is only one real root it makes sense to take an initial value inside this interval, for example $x_0=1/2$.
I don't see why you need a complicated procedure. The easiest way (for me) appears to be fixed point iteration:
$$x_n=\frac{1+2 \cos x_{n-1}}{5}$$
$$x_0=\frac{1}{2}=0.5$$
$$x_1=\color{blue}{0.5}51033024756149$$
$$x_2=\color{blue}{0.54}0793647370719$$
$$x_3=\color{blue}{0.542}920147441434$$
$$x_4=\color{blue}{0.542}481469458663$$
$$x_5=\color{blue}{0.5425}72091664505$$
The root is:
$$x=\color{blue}{0.5425565799894813}$$
If you need faster convergence, you can of course use another method.