Answer: I think this can be best "visualized" if you consider X as a topological space where the topology is induced by a metric, e.g. $X = \mathbb{R}^2$ with the topology induced by the standard Euclidean metric (i.e $\mathbb{R}^2$ with the topology that is formed by open $\epsilon$-balls). Then, the closure $\bar A$ of a set $A$ contains "all points that are arbitrarily close to points of $A$", including points in $A$ itself. In other words, $\bar A$ contains $A$ and all its boundary points. If you take for example $A$ as the open unit ball $B_1(0) \subset \mathbb{R}^2$ centered at $0$, then the "points that are arbitrarily close to $B_1(0)$" are exactly the ones that lie on the unit circle centered at $0$.
What Munkres now proves is the contraposition of what I said above: He shows that a point $x \in X$ that is not arbitrarily close to $A$ can't be contained in $\bar A$, and vice-versa. If your $x$ is not arbitrarily close to $A$, then you can always find a mini-mini open $\epsilon$-ball $B_\epsilon(x)$ centered at $x$ such that no points of $B_\epsilon(x)$ lie inside $A$, i.e. $B_\epsilon(x)$ doesn't intersect $A$. On the other side, if you have a point $x$ and an open $\epsilon$-ball $B_\epsilon(x)$ that doesn't intersect $A$, then $x$ can't be arbitrarily close to $A$, hence $x \notin \bar A$.
You can also state the theorem intuitively without using contraposition: If you have a point $x$ such that every open $\epsilon$-ball $B_\epsilon(x)$ around $x$ intersects $A$ no matter how small $\epsilon$ is, then $x$ must be arbitrarily close to $A$, hence $x \in \bar A$. And if $x \in \bar A$, then $x$ is arbitrarily close to $A$, hence every open $\epsilon$-ball $B_\epsilon(x)$ must intersect $A$.
This description translates to arbitrary topological spaces where the open $\epsilon$-balls are just open sets defined by the topology on the space. However, you don't have always a metric on a topological space that gives you an exact notion of distance, but in fact the topology gives an abstract sense of "distance" by defining open sets.
I hope that my words could "catch" a bit the intuition about the theorem.
Note: The reason why Munkres proves the theorem by contraposition is that he only has to find one open neighborhood of a point $x \notin \bar A$ that doesn't intersect $A$ to conclude the $\Rightarrow$-direction, whereas without contraposition he has to show that every possible open neighborhood of $x \in \bar A$ has to intersect $A$ to conclude the $\Rightarrow$-direction, and there can be quite a lot of open neighborhoods around a point $x \in \bar A$, depending on the topology.