An integer $\,n\,$ is even or odd since, by the division algorithm, $\,n\,$ has a unique remainder $0$ or $1$ when divided by $2$. By definition $\,n\,$ is even if it has remainder $0$ and odd if it has remainder $1$.
Similarly many other simply-stated problems have very short, simple proofs. But this does not imply that all simply-stated problems necessarily have simple proofs. Indeed, as you mention there are simple open problems such as the Collatz conjecture that have eluded proof.
It is a common false hunch that simple (short) statements should have short proofs. This is easily refuted using only rudimentary logic. For any formal system that has nontrivial power (e.g. Peano arithmetic) there is no recursive algorithm that decides theoremhood. This implies that there is no recursive bound on the length of proofs (if $\,L(n)\,$ bounds the length of proofs of a statement of length $\,n,\,$ then we could test for theoremhood simply by enumerating and testing all possible proofs of length $\,\le L(n)).\,$ Therefore there exist short-stated theorems with proofs so immensely long that they are probably not amenable to human comprehension (these results date back to Goedel's 1936 paper on speedup theorems).
It remains to be seen if there exist mathematically interesting theorems like this. There may be examples in Collatz-like congruential iterations (similar to the difficult open $3 x+1$ problem) that were discovered in the wild while analyzing Busy Beaver holdout machines (while attempting to find the smallest universal Turing machines). John Conway has shown that there exists similiar simple congruential iterations with undecidable halting problem. That such undecidable problems may be encoded so succinctly in programs for tiny Turing machines should not come as a surprise to anyone familiar with the above simple results from logic. They are a testament to the power of ingenuity - whether it be human (in powerful mathematical theories) or nature (the DNA-based programs designed by evolution).