If $0\le x\le 1$ then $\dfrac 1 3 \le \dfrac 1 {2+1^2} \le \dfrac 1 {2+x^2} \le \dfrac 1 {2+0^2} = \dfrac 1 2$.
If $1\le x \le 2$ then $\dfrac 1 6 \le\dfrac 1 {2+x^2} \le \dfrac 1 3 $.
Therefore
$$
\frac 1 3 + \frac 1 6 \le \int_0^1 \frac{dx}{2+x^2} + \int_1^2 \frac{dx}{2+x^2} \le \frac 1 2 + \frac 1 3.
$$
As for Wolfram Alpha, notice that the integral is easily evaluated in closed form:
\begin{align}
& \int_0^2 \frac{dx}{2+x^2} = \frac 1 2 \int_0^2 \frac{dx}{1 + \left(\frac x {\sqrt 2}\right)^2} = \frac{\sqrt 2} 2 \int_0^2 \frac{dx/\sqrt 2}{1+\left( \frac x {\sqrt2} \right)^2} = \frac {\sqrt 2} 2 \int_0^{\sqrt 2} \frac{du}{1+u^2} \\[10pt]
= {} & \frac{\sqrt 2} 2 \left( \arctan \sqrt 2 - \arctan 0 \right) = \frac{\sqrt 2} 2 \arctan \sqrt 2.
\end{align}