Used symbol $\theta = \angle ABE$ as it is a variable. Agreement with OP's value of $\theta = 6^0$ for $ \alpha = 30^0$ obtained as follows.

$ BEDF$ is a cyclic quadrilateral with $BF$ as diameter. A construction of the circum(semi-)circle is suggested and found helpful.Hand sketch (Paint) is not to scale.Axes are tilted in graph as shown keeping $EF$ horizontal.Triangle $ABE$ is isosceles, the two important angles equal those in alternate semi-circular segment.
A general derivation to relate $ \alpha= \pi/6$ (in this case) to find/relate to $ \theta $ is given :
Coordinates of E: $ (L \tan \theta , L )\tag{1} $
Equation of EG by Polar Normal form for a straight line :
$$ x \cos (\pi/2- \theta) + y \sin (\pi/2- \theta) = L\sec \theta $$
$$ x \sin \theta + y \cos \theta = L\sec \theta \tag{2}$$
Solving (1),(2) by Cramer's Rule two unknowns to get coordinates of $F$.
$$x_F= N_x/\Delta = L(\sec \theta - 2 \cos \theta)/\Delta,\,\, y_F= N_y/\Delta = L(- 2 \sin \theta- \tan \alpha \sec \theta )/\Delta;\,\tag{3} $$
where
$$\Delta = (\sec \theta - \tan \alpha \cos \theta) $$
$$ EF^2 = (x_F- L \tan \theta )^2 + ( y_F- L)^2 = 4 L^2 \tag{4} $$
$$ (N_x/\Delta-\tan \theta))^2 +(N_y /\Delta-1 )^2 = 4 \tag{**5**} $$
which is the required relation implicit in $\alpha,\theta $. The numerical solution is obtained that could be applied for a range of similar problems. To check out its use that way some solution pairs that have integral degree combinations:
$$ (\alpha, \theta)=( \approx 26.56505,0^0), (30^0,6^0), (36^0,18^0), (40^0,70^0),(45^0,60^0+ 4 \pi)... \tag{6} $$
I was curious about such $ (\pi/n, \pi/m ) $ possible combinations.So far only above three pairs are found to be at all possible with integer values in degrees.The plot has two curves, all combinations are found in the vertical arm. Geometrical meaning of the more horizontal curve is not yet clear. However, it is outside the scope of question OP asks, I attempted a generalization.
EDIT1:
An admittedly more direct/simpler way following OP's procedure gets us to :
$$ 2 \cos \theta \sin (\alpha - \theta) - \sin ( 2 \alpha - \theta) =0 $$
A solution in fourth order trig equation $ \theta = f( \alpha) $ may be possible in closed form. Else may be left in the implicit form for numerical iteration. Its Contour graph is also included. The matter why they appear different (crossing vs. non-crossing) still needs attention.