The extraordinary Roth’s theorem (which won the Fields Medal for Roth) is the following:
“For all algebraic irrational $\alpha$ and all $\epsilon \gt 0$, the inequality
$$\left|\alpha-\frac pq\right|\lt\frac{1}{q^{2+\epsilon}}$$ has only a finite number of solutions in rational irreducible $\frac pq$, which implies that, for all $\epsilon\gt 0$, there is a constant $C(\alpha,\epsilon)$ such that $$\left|\alpha-\frac pq\right|\gt \frac{ C(\alpha,\epsilon)}{ q^{2+\epsilon}}$$ for all rational $\frac pq$ with $q\gt 0$.
It is important to notice that the constant $C(\alpha,\epsilon)$ is not effective, and that this is a typical theorem of existence. But the main fact is that the irrational $\alpha$ must be algebraic, which is not so in the case of the transcendental number $\pi$.
It may be pertinent to add that the measure of irrationality of $\pi$ is known to be less than or equal to $7.6063$ (Salikov), and conjecturally less than or equal to $2.5$ (Alekseyev); and probably could be equal to $2$, as for irrational algebraic numbers and particularly for the transcendental $\mathrm e$, whose measure of irrationality is exactly $2$.