How about this.
Suppose there are infinite $s_{n}$'s in the sequence $\{s_{n}\}$ such that $s_{n} \geq x$.
Let $\{s_{n_{k}}\}$ be the subsequence of $\{s_{n}\}$ consisting of the $s_{n}$'s that are greater or equal to $x$. Then there are two possibilities:
(i). If $\{s_{n_{k}}\}$ is bounded above, then there exists a real number $y$ such that $y \in E$ and $y \geq x$.(By theorem 3.6-[b] and the fact that we cannot have a subsequence of $\{s_{n_{k}}\}$ that converges to a number less than $x$.) Notice that we have $x > s^{*}$, which implies $y \geq x > s^{*}$, then $s^{*}$ is no longer an upper bound.(A contradiction).
(ii). If $\{s_{n_{k}}\}$ is not bounded above, then we must have $+\infty \in E$.(See the lemma below). Since $+\infty \geq x$ by definition, we get $+\infty \geq x > s^{*}$, which implies, again, that $s^{*}$ is not an upper bound. A contradiction.
Therefore, there are only finite $s_{n}$'s in the sequence $\{s_{n}\}$ such that $s_{n} \geq x$. That is, there exists an integer $N$ such that $n \geq N$ implies $s_{n} < x$.
You may find this result useful:
Lemma: If a sequence $\{s_{n}\}$ is not bounded above, then there is a subsequence of $\{s_{n}\}$ that converges to $+\infty$.
We can construct a subsequence $\{s_{n_{k}}\}$ that converges to $+\infty$ like this: Let $s_{n_{k}} > k$ for all $k \in \mathbb{N}$ with $n_{1} < n_{2}<\dots$. (Can we do this? If there was no $n_{1}$ such that $s_{n_{1}} > 1$, then $s_{n} \leq 1$ for all $n$, a contradition. After we have chosen $s_{n_{1}}, s_{n_{2}}, \dots$, choose $s_{n_{k}}$ such that $n_{k} > n_{k-1}> \dots > n_{1}$ and $s_{n_{k}}>k$. If there was no such $s_{n_{k}}$ available, then $s_{n_{k}} \leq k$ for all $n > n_{k-1}$. Therefore, $\{s_{n}\}$ is bounded by $\max \{s_{1}, \dots, s_{n_{k-1}}, k\}$, a contradiction. Therefore, we can indeed construct such an sequence $\{s_{n_{k}}\}$ as desired.) Now, notice that for all $M \in \mathbb{R}$, there exists an integer $N$ such that $n_{k} \geq N$ implies $s_{n_{k}} \geq M$. Hence $s_{n_{k}} \to +\infty$, as desired.