Well, here's a way to do it. Maybe over kill.
Let $S = A \times A$. That is the universal relationship.
As $(x,x) \in S$ for all $x$ it is reflexive. Let's destroy that be removing $(a,a)$.
$T = A \times A \setminus \{(a,a)\}$.
$T$ is not reflexive because $a \not T a$.
But if $x T y$ then $y T x$. So T is symmetric. Let's kill that. Let's remove $(a,b)$.
$W = A \times A \setminus \{(a,a),(a,b)\}$
Not $W$ is not symetric because $b W a$ but $a \not W b$.
Is $W$ transitive? To be honest, I'm not sure. But $a R c$ and $c W d$ and $a W d$. Let's remove $(a,d)$.
Let $R = A \times A \setminus \{(a,a),(a,b),(a,d)\}$
$R$ is not transitive because $a R c$ and $c R d$ but $a \not R d$.
And it's not symmetric as $a \not R a$ nor reflexive as $b R a$ but $a \not R b$.
Or we could have built from scratch;
$S = \{(a,b)\}$
Not reflexive: $a \not S a$.
Not symmetric: $a S b$ but $b \not S a$.
Transitive? Vacuously so. There are no $x S y$ and $y S z$. So for all zero of those it is vacuously true $x S y; y S z \implies x S z$.
But let's kill this by adding $R = \{(a,b),(b,c)\}$
Then we have $a R b$ and $b R c$ but $a \not R c$ so it is not transitive.