It's not surjective in general. Consider the topologist sine curve $S$
$$S = \left\{\left(x, \sin \bigg(\frac{1}{x}\bigg)\right),\ 1/\pi\geq x>0\right\}$$
together with the interval $A = \{(0, t): |t|\leq 1\}$ and a curve $C$ joining this interval to the point $(1/\pi, 0)$. Call $X = A \cup S\cup C$. Then this is simply connected and $X/A$ is homeomorphic to $\mathbb S^1$, thus the induced map is zero.
Remark: To see that $X/A$ is homeomorphic to $\mathbb S^1$ Let $L = \{ (t,0) : t\in [0,1]\}$. Then $\mathbb S^1$ is homeomorphic to $B:=L\cup C$. Define $ F : X\to B$ by
$$F(x_1, x_2) = \begin{cases} (x_1,0) & \text{if } (x_1, x_2) \in A\cup S, \\ (x_1, x_2) & \text{if } (x_1, x_2) \in C. \end{cases}$$
One can check that $F$ is continuous and $f(A) = \{ (0,0)\}$. Thus $F$ descends to a continuous mapping $f: X/A \to \mathbb S^1$ which is bijective. Since $X/A$ is compact (Since $X$ is) and $\mathbb S^1$ is Hausdorff, $f$ is a homeomorphism.