There is a general method to answer this kind of question, which Rogers called the Tarski-Kuratowski computation in his book. You first write down a definition of the set in the arithmetical hierarchy, in which all the leading quantifiers explicitly shown in prenex form and in which the central "matrix" is decidable:
$$
e \in \text{Fin} \Leftrightarrow (\exists k)(\forall i)(\forall s) [ \phi_{e,s}(i)\mathord{\downarrow} \Rightarrow i < k]$$
Here as usual $\phi_{e,s}(i)\downarrow$ says that $\phi_e(i)$ halts in no more than $s$ steps, which is a decidable question.
From this, we see that the set Fin is $\Sigma^0_2$. That means you should next try to show the set is $\Sigma^0_2$ hard, at which point you will know the set is $\Sigma^0_2$ complete. In particular, that would mean the set is not r.e. because the r.e. sets are exactly the $\Sigma^0_1$ sets, and a $\Sigma^0_2$ hard set cannot be $\Sigma^0_1$.
In practice, most sets that arise in practice will be complete for the level of the arithmetical hierarchy that the natural prenex form of the set suggests ($\Sigma^0_2$, in this case). That is why this method is worth knowing.
The thing that remains is showing that the set Fin is $\Sigma^0_2$ hard. To do that, suppose you have a $\Sigma^0_2$ formula $\psi(x) \equiv (\exists n)(\forall m)\phi(n,m,x)$. Given $x$, we need to make a program $e = e(x)$ that will be in Fin if and only if $\psi(x)$ holds. That is not too hard to do, using the fact that $\phi(n,m,x)$ is decidable from $n$, $m$, and $x$. I'll leave it to you.
It also helps to know some examples of particular sets at particular levels of the hierarchy:
- The halting set $\{e : \phi_e(0)\mathord{\downarrow}\}$ is $\Sigma^0_1$ complete, and its complement is $\Pi^0_1$ complete.
- Fin is $\Sigma^0_2$ complete. So is the set of programs that compute non-total functions.
- The complement of Fin is the set of programs with infinite domain. This set is $\Pi^0_2$ complete. So is the set of programs that compute total functions.
- The set of programs whose domain is cofinite is $\Sigma^0_3$ complete. Its complement, the set of programs which diverge on an infinite set of inputs, is $\Pi^0_3$ complete.
Once you know these, you can use them to show other sets are at particular levels of the arithmetical hierarchy.