Herein, we present a systematic approach to the problem of interest. To that end we now proceed.
Note that for $\theta\in [(n-1/2)\pi,(n+1/2)\pi]$, we have
$$\bbox[5px,border:2px solid #C0A000]{\arcsin(\sin(\theta))=(-1)^n(\theta-n\pi) }\tag 1$$
Let $\theta=\pi/2-2x$ in $(1)$.
CASE $1$: $\displaystyle x\in[\pi/2,\pi]$
If $x\in [\pi/2,\pi]$, then $\theta\in[-3\pi/2,-\pi/2]$. Using $(1)$ with $n=-1$ reveals
$$\begin{align}
\arcsin(\cos(2x))&=\arcsin(\sin(\theta))\\\\
&=-(\theta+\pi)\\\\
&=-(\pi/2-2x+\pi)\\\\
&=2x-3\pi/2
\end{align}$$
CASE $2$: $\displaystyle x\in[\pi,3\pi/2]$
If $x\in [\pi,3\pi/2]$, then $\theta\in[-5\pi/2,-3\pi/2]$. Using $(1)$ with $n=-2$ reveals
$$\begin{align}
\arcsin(\cos(2x))&=\arcsin(\sin(\theta))\\\\
&=\theta+2\pi\\\\
&=\pi/2-2x+2\pi\\\\
&=5\pi/2-2x
\end{align}$$