When it comes to propositional logic, students often get caught up in the details and forget the meanings - which is unfortunate, because if you can think clearly about the meanings behind the sentences you're working with, the answer is often obvious. "$a \implies \mathrm{false}$" says, literally, "if $a$ is true, then false is true". "False is true" is nonsense - it's something we know to be false. If I tell you "if it's raining outside then the moon is made of green cheese", what can you conclude about the weather? If it were raining, then the moon would be made of green cheese. Since the moon is not made of any sort of dairy product, this is clearly an impossible state of affairs - so it must not be raining. Likewise, if we know $a \implies \mathrm{false}$, then we can conclude that $a$ is false.