Let $x_1 = max\{x_1, x_2, \cdots, x_k\}$.
Then we have that
$$
\lambda_1x_1 + \lambda_2x_2 + \cdots \lambda_kx_k = x_1 \\
\lambda_1 + \lambda_2 + \cdots + \lambda_k = 1
$$
$$
\lambda_1x_1 + \lambda_2x_2 + \cdots \lambda_kx_k = x_1 \ (1) \\
\lambda_1x_1 + \lambda_2x_1 + \cdots + \lambda_kx_1 = x_1 \ (2).
$$
Take $(1) - (2)$ to get that
$$
\lambda_2 (x_2-x_1) + \lambda_3 (x_3 - x_1) + \cdots + \lambda_k (x_k - x_1) = 0.
$$
which can be written as
$$
\sum_{i=2}^{k} \lambda_i (x_i - x_1) = 0.
$$
Since $\lambda_i > 0$ and $x_i - x_1 \leq 0$ we have that $\lambda_i (x_i - x_1) \leq 0$. From where we conclude that $\lambda_i (x_i - x_1) = 0$.