As there was no solution to this old problem (more than two years old), I have written this one. I find back a solution mentionned by @Michael Hoppe.
I transform expression $\sin(\alpha)+\sin(\beta)+\sin(\gamma)$ with constraint $\alpha+\beta+\gamma=1$ under the form :
$$\sin(\alpha)+\sin(\beta)+\sin(\pi -(\alpha+\beta))$$
i.e.,
$$f(\alpha,\beta):=\sin(\alpha)+\sin(\beta)+\sin(\alpha+\beta).$$
A basic patch of this doubly periodical function (separately periodical for variable $\alpha$ and variable $\beta$) is represented on Fig. 1. In fact the minimum must occur along the intersection of the surface with vertical plane with equation $y=x$ (see Appendix below).
Thus it suffices to study the minimum of function
$$\varphi(\theta):=f(\theta,\theta)=2 \sin(\theta)+\sin(2 \theta).$$
Let us determine the extrema of $\varphi$. The occur for values of $\alpha$ such that :
$$\varphi'(\theta)=2 \cos(\theta)+2 \cos(2 \theta)=0$$
This equation can be transformed into $\cos(\theta)=-\cos(2 \theta)$ then into $\cos(\theta)=\cos(\pi-2 \theta)$ whence 2 cases :
(a) $\theta=\pi-2\theta + k 2 \pi$ yielding $\theta=\pi/3+k 2 \pi/3$, or
(b) $\theta=-(\pi-2\theta) + k 2 \pi$ yielding $\theta=\pi + k 2 \pi$ (that is in fact included into case (a)).
It means that there are potentially 3 solutions :
$$\theta_1=\pi/3, \ \ \ \theta_2=\pi, \ \ \ \theta_3=5 \pi/3.$$
In fact, as can be verified on the figure, case $\theta_1$ corresponds to a maximum and case $\theta_2$ corresponds to an inflexion point (a stationnary point in 3D). Only case $\theta_3=5 \pi/3$ gives a minimum.
Thus, the solution is for any $k \in \mathbb{Z}$
$$\alpha=\beta=5\pi/3+k 2 \pi, \gamma=\pi-(\alpha+\beta)=-7 \pi/3 - k 2 \pi$$
that can be given the following simpler equivalent form :
$$\alpha=\beta=-\pi/3+k 2 \pi, \gamma=\pi-(\alpha+\beta)=5\pi/3 - k 4 \pi$$

Fig. 1 : Surface $z=f(x,y)$ with curve of function $\varphi$ traced on it.
Appendix : Why do the minimum must appear for values of $\alpha, \beta$ such that $\alpha=\beta$ ?
Let us work with $\alpha+\beta=const. = c$ (up to a multiple of $2 \pi$).
If such is the case, differentiating $f(\alpha,\beta)=\sin(\alpha)+\sin(c-\alpha)+\sin(c)$ gives $\cos(\alpha)-\cos(c-\alpha)$ which is $0$ iff
- either $\alpha=c - \alpha +k 2 \pi \ \iff \ \alpha=\frac{c}{2}+k \pi$, meaning that $\alpha=\beta=\frac{c}{2}+k \pi$.
- or $\alpha=-(c - \alpha) +k 2 \pi$ which happens in the very particular case where $c=k 2 \pi$.
Edit : it is possible that there is a solution using the (classical) identity you mention
$$f(\alpha,\beta,\gamma):=\sin \alpha+\sin \beta+\sin \gamma = 4\cos \frac{\alpha}{2}\cos \frac{\beta}{2}\cos \frac{\gamma}{2}$$
valid under the constraint $\alpha+\beta+\gamma=\pi$... but I don't see how...