As for your choice of cellular structure, we have the complex
$$
0 \longrightarrow C_2 \longrightarrow C_1 \longrightarrow C_0\longrightarrow 0
$$
where the chain modules are given as
$$
C_2 = \mathbb Z e_2, \qquad C_1 = \mathbb Z e_1, \qquad C_0 = \mathbb Z e_0,
$$
and the maps are given as (always according to your definitions)
$$
\partial _2: \mathbb Z e_2 \longrightarrow \mathbb Z e_1
$$
$$
\partial _2(e_2) = 2 e_1
$$
and
$$
\partial _1: \mathbb Z e_1 \longrightarrow \mathbb Z e_0
$$
$$
\partial _1(e_1) = e_0 - e_0 = 0.
$$
So, cellular homology turns out to be
$$
H_2 = \ker \partial _2 = 0, \qquad H_1 = \frac {\ker \partial _1}{\text {Im }\partial _2} = \frac {\mathbb Z}{2\mathbb Z} = \mathbb Z_2, \qquad H_0 = \mathbb Z ,
$$
with representatives $\ [e_1]\ $ and $\ [e_0]. \ $ Of course $\ 2 [e_1] = 0.$
As for your choice of simplicial structure, we have the complex
$$
0 \longrightarrow C'_2 \longrightarrow C'_1 \longrightarrow C'_0\longrightarrow 0
$$
where the chain modules are given as
$$
C'_2 = \mathbb Z U \oplus \mathbb Z L, \qquad C'_1 = \mathbb Z a\oplus \mathbb Z b\oplus \mathbb Z c, \qquad C'_0 = \mathbb Z v \oplus \mathbb Z w.
$$
For the maps, we have to choose an orientation for the $2$-"simplexes" $U\ $ and $\ L. \ $ I choose counter-clockwise for $U\ $ and clockwise for $\ L: \ $ this choice makes everything simpler, but is not necessary.
The boundary maps are
$$
\partial '_2: \mathbb Z U \oplus \mathbb Z L \longrightarrow \mathbb Z a\oplus \mathbb Z b\oplus \mathbb Z c
$$
$$
\partial '_2(U;0) = (-a;b;c), \qquad \partial '_2(0;L) = (a;-b;c).
$$
You can see this on your picture, for my choice of orientations.
$$
\partial '_1: \mathbb Z a\oplus \mathbb Z b\oplus \mathbb Z c \longrightarrow \mathbb Z v \oplus \mathbb Z w
$$
$$
\partial '_1 (a;0;0) = (-v;w), \qquad \partial '_1 (0;b;0) = (-v;w) \qquad \partial '_1 (0;0;c) = (0;0).
$$
The last follows from the fact that $\ \partial '_1 c = v-v.$
So, again:
$$
\ker \partial '_2 = \{(hU;kL) \in C'_2 / \partial '_2 (hU;kL) = (0;0;0) \},
$$
that is
$$
-h+k = 0, \qquad h - k = 0, \qquad h+k = 0.
$$
This is trivially seen to imply $\ h=k=0.$
As we are here, note that $\ \partial '_2 (U;L) = (0;0;2c).$
$$
\ker \partial '_1 = \{(la;mb;nc) \in C'_1 / \partial '_1 (la;mb;nc) = (-(l+m)v;(l+m)w) = (0;0) \},
$$
so
$$
l+m = 0 \iff l=-m
$$
and
$$
\ker \partial '_1 = \{(-m;m;n) \ \forall m, n \in \mathbb z \}.
$$
$$
\text {Im} \partial '_2 = \{(-h+k;h-k; h+k)\ h,k \in \mathbb Z \}.
$$
Notice that $h-k\ $ and $h+k \ $ have the same parity, so this is not all of the kernel of $\partial '_1: \ $ we can see that if $m $ and $n$ do not have the same parity, they are not in the image, while if they do, we can find $h$ and $k:$
$$
h-k = m \qquad h+k = n, \iff h = k + m \qquad 2k + m = n \iff 2k = n - m.
$$
So
$$
\frac {\ker (\partial '_1 )}{\text {Im} (\partial '_2)} = \mathbb Z_2.
$$
As for $H_0$, of course Im$(\partial '_1 ) = \{(-sv;sw), \ s \in \mathbb Z\},\ $ which is $\ \mathbb Z.$
As representatives for the homology classes, we can take $(0;0;c)\ $ (it is a cycle, but, since $0$ and $1$ do not have the same parity, not a boundary,) and $(v;0).$
So, we are ready for our explicit chain complexes homomorphism which induces an isomorphism in homology:
$$
f_* : C_* \longrightarrow C'_*
$$
$$
f_2 : e_2 \longrightarrow (U;L)
$$
$$
f_1 : e_1 \longrightarrow (0;0;c)
$$
$$
f_1 : e_0 \longrightarrow (v;0)
$$
Check commutativity: $f_1 \circ \partial _2 (e_2) = f_1 (2 e_1) = (0;0;2c); \ \partial' _2 \circ f_2 (e_2) = \partial' _2 (U;L) = (0;0;2c). \ $ Seen before.
$f_0 \circ \partial _1 (e_1) = f_0 (0) = (0;0); \ \partial' _1 \circ f_1 (e_1) = \partial' _1 (0;0;c) = (0;0). \ $ This map induces an isomorphism in homology because $\ f_*([e_1]) = [(0;0;c)]\ $ and $\ f_* ([e_0]) = [(v,0)], \ i. e. \ $ sends representatives to representatives.