It would be simpler to look for the zeros of function
$$f(\omega)=\left(b^2 \omega ^2-1\right) \sin (\omega )-2 b \,\omega\, \cos (\omega )$$ which does not show any discontinuity.
Focusing on the first postive root, series expansion followed by power series reversion gives, as an approximation,
$$\omega=t+\frac {20 b^2+10 b+1}{40(6 b^2+6 b+1 ) } t^3+$$ $$\frac {48720 b^4+45360 b^3+15300 b^2+2140 b+107}{67200(6 b^2+6 b+1 )^2}t^5+O(t^7)$$where
$$t=\sqrt{\frac{6 (2 b+1)}{6 b^2+6 b+1} }$$
As shown below, the approximation is decent (it could be improved at the price of more terms in the initial series expansion).
$$\left(
\begin{array}{ccc}
b & \text{estimate} & \text{solution} \\
0.05 & 2.69706 & 2.85774 \\
0.10 & 2.49284 & 2.62768 \\
0.15 & 2.32792 & 2.43990 \\
0.20 & 2.19140 & 2.28445 \\
0.25 & 2.07603 & 2.15375 \\
0.30 & 1.97688 & 2.04223 \\
0.35 & 1.89049 & 1.94582 \\
0.40 & 1.81433 & 1.86151 \\
0.45 & 1.74654 & 1.78704 \\
0.50 & 1.68568 & 1.72067 \\
0.55 & 1.63066 & 1.66106 \\
0.60 & 1.58059 & 1.60715 \\
0.65 & 1.53479 & 1.55811 \\
0.70 & 1.49267 & 1.51325 \\
0.75 & 1.45378 & 1.47201 \\
0.80 & 1.41772 & 1.43394 \\
0.85 & 1.38417 & 1.39866 \\
0.90 & 1.35285 & 1.36584 \\
0.95 & 1.32353 & 1.33521 \\
1.00 & 1.29600 & 1.30654 \\
\end{array}
\right)$$
In any manner, with these estimates, Newton method converges in a couple of iterattions.