To show that $L$ is recursively enumerable, we just need to construct a Turing Machine $N$ that receives as input the encoding of a Turing machine $M$, with the following specification:
- If $M$ accepts $\epsilon$, then $N$ must accept $M$.
- Otherwise, $N$ can reject or loop forever.
We construct $N$ so that it simulates $M$ on input $\epsilon$. If $M$ ever terminates, $N$ gives the same answer as $M$. Note that this respects the specification above.
The only thing we need to do is to simulate $M(\epsilon)$. This is what your friend meant when he said that we know it is recursively enumerable because $M(\epsilon)$ can be simulated.