In the given question the last point is the valid first order formula:
We can prove this by using law of contradiction and Rule of Inference (Modus Ponens specifically). The TT or boolean alzebra methods will be a bit difficult to apply in case of Predicate Logic, therefore your method of taking α as 0 = 0, β as 0 = 1 would be a little herculean.
Proof:
Let the consider the LHS to be true i.e.
[(∀x)[α⇒β]] is true
which means
α1 => β1, α2 => β2, α3=> β3, ..., αn => βn are true. Now we have to prove the RHS to be false
Also, in implication we can write A => (B => C) as (A ^ B) => C
Therefore we can write, [(∀x)[α⇒β]]⇒[((∀x)[α]) as [(∀x)[α⇒β]] ^ [((∀x)[α]).
Now using Rule of detachment (Modus Ponens) i.e. If (p => q and p) => q
we can prove that [(∀x)[α⇒β]] ^ [((∀x)[α]) => (∀x)[β]).
Note, here if we want to make RHS false by any means; we will not be able to. Therefore; ~F = T (Proof by contradiction)
Also, notice the first Option is the converse of the 4th option and is not valid. And other two options are vaguely out of order.