Notations are from John M.Lee's book Introduction to smooth manifolds. $\mathbb{R}_a^n=\{a\}\times \mathbb{R}^n=\{(a,v):v \in\mathbb{R}^n\}$ $D_v|a:C^\infty(\mathbb{R}^n\to\mathbb{R})$,$f\mapsto \frac{d}{dt}|_{t=0}f(a+tv)$.
Since the directional derivative is the same with respect to some direction $v$ and $2v$, i.e., the map from geometric tangent space to tangent space of $\mathbb{R}^n$ is not injective, it cannot be an isomorphism. However, a prove can be found on any book that it is isomorphism. Where I am wrong? thanks