Let's start with a simple polynomial $f(x) = x^{3} - 2 \in \mathbb{Q}[x]$. It is known that $f$ is irreducible in $\mathbb{Q}[x]$ and hence without any further information (i.e. working in field $\mathbb{Q}$ and ring $\mathbb{Q}[x]$) we can not distinguish the $3$ roots of $f$. The distinction between roots is only possible once we have the splitting field of $f$ available.
Now consider the quotient $\mathbb{Q}[x]/(f(x))$ which is a field (because $f$ is irreducible) and this field contains a member $x + (f(x))$ which is a root of $f(x)$. Moreover this field is isomorphic to $\mathbb{Q}(\sqrt[3]{2})\subset \mathbb{R}$.
Why is this extension field obtained using quotient by $(f(x))$ give us the real root $\sqrt[3]{2}$ and not one of the other two roots? I mean while taking the quotient with $f$ we are just getting an extension field which depends on $\mathbb{Q}$ and $f(x)$ and we don't know for sure which of the three roots it will contain.
The same question however does not apply to all irreducible polynomials. Thus if we take $f(x) = x^{4} + x^{3} + x^{2} + x + 1$ (or more simply $x^{2} + 1$) then $\mathbb{Q}[x]/(f(x))$ contains all the roots of this polynomial.
Update: For the simple polynomial $x^{2} + 1$ I can show that both of its roots are in the extension field $\mathbb{Q}[x] / (x^{2} + 1)$. With some reasonable effort we can show the same for $f(x) = x^{4} + x^{3} + x^{2} + x + 1$. I think we can also show that for $f(x) = x^{3} - 2$ the field $\mathbb{Q}[x]/(f(x))$ has only one root (I have not yet proved this for myself but I am sure I can).
My real question is that even if we assume that this field has only one of the roots how do I know that this particular root is special and other two roots are more of a similar nature (ie this one is real and others are complex conjugates)?
It appears I have been misunderstood so I add more formalism and details. Let $K$ be the splitting field of $x^{3} - 2 \in \mathbb{Q}[x]$. So $K$ has three elements $a, b, c$ each of which is a cube root of $2$ in $K$. Also we have $$K \supset \mathbb{Q}[x]/(x^{3} - 2) = L \supset \mathbb{Q}$$ My point is that the roots $a, b, c \in K$ are not indistinguishable from each other. Precisely we have one of these (say $a$) in $L$ and rest two ($b, c$) in $K$. Also there is automorphism $\sigma$ of $K$ which fixes $\mathbb{Q}$ and $\sigma(b) = c$. But there is no automorphism of $K$ which fixes $\mathbb{Q}$ and sends $a$ to $b$ (or $c$). I know this only by working in field $\mathbb{C}$. How do I know this without working in $\mathbb{C}$?
Thanks to DonAntonio, I understood the flaw in my reasoning. Also sorry to other people who answered for bearing with my nonsense comments. What I gather from the overall discussion is this:
Summary: The cubic $x^{3} - 2$ has three roots and they all lie in splitting field $K$. The intermediate field $L = \mathbb{Q}[x]/(x^{3} - 2)$ contains only one of the roots (see last part of egreg's answer as to why $L$ can't have all the roots) and it is not possible to determine via algebra as to which of $a, b, c$ lie in $L$. Thus $a, b, c$ are indeed indistinguishable and any one (say $a$) can be supposed to lie in $L$ and the rest lie in $K$. And we can then prove that $K = L(b) = L(c)$ and $L = \mathbb{Q}(a)$ and $L$ is of degree $3$ over $\mathbb{Q}$ and $K$ is of degree $2$ over $L$. I think it is now easy to get the Galois group and show that it is indeed $S_{3}$.