Below I have shown that the second relation is symmetric and that the third relation is not symmetric. Hopefully this will provide some insight and you will be able to determine whether the remain three relations are symmetric.
For 2. define $x \sim y$ iff (x-y) is even.
To show that $\sim$ is symmetric, we have to show that for all $x,y \in \mathbb{Z}$, if $x \sim y$, then $y \sim x$. Thus let $x,y \in \mathbb{Z}$ be integers such that $x \sim y$. This means that $(x-y)$ is even. $(x-y)$ being even means that there exists a $k \in \mathbb{Z}$ such that $(x-y) = 2k$.
Now note that $(y-x) = (-x+y) = -(x-y) = -2k = 2(-k)$. Thus $(y-x)$ is an even integer and $y \sim x$ holds.
Note that there was nothing special about $x,y$ (other than assuming $x \sim y$), thus we know that whenever $x \sim y$ is true, $y \sim x$ is true and hence $\sim$ is symmetric.
For 3. define $x \sim y$ iff (x+2y) is positive.
I claim that $\sim$ is not symmetric. To show that a relation is not symmetric, we must find two integers $x,y \in \mathbb{Z}$ such that $x \sim y$ is true but $y \sim x$ is false.
If we let $x = -1$ and $y = 1$, we have that $x+2y = -1+2 =1>0$, thus $x \sim y$ is true. However $y + 2x = 1 + 2(-1) = 1-2 = -1 < 0$, thus $y \sim x$ is false. This shows that $\sim$ is not symmetric.