Denote $e_1 = \begin{bmatrix}1\\0\end{bmatrix}$ and $e_2 = \begin{bmatrix}0\\1\end{bmatrix}$.
Let the matrix in question be $A$.
Observe that $A = \begin{bmatrix}I&I\\I&I\end{bmatrix}$, where $I = \begin{bmatrix}1&0\\0&1\end{bmatrix}$.
Then, $A$ is similar to $B = \begin{bmatrix}1&1\\1&1\end{bmatrix}$, whose eigenvalues are easily found by the determinant method:
$$\begin{array}{rcl}
\det(B-\lambda I) &=& 0 \\
(1-\lambda)^2 - 1 &=& 0 \\
\lambda^2 - 2\lambda &=& 0 \\
\lambda(\lambda - 2) &=& 0 \\
\end{array}$$
Or from inspection: $B\begin{bmatrix}1\\1\end{bmatrix} = \begin{bmatrix}2\\2\end{bmatrix}$ and $B\begin{bmatrix}1\\-1\end{bmatrix} = \begin{bmatrix}0\\0\end{bmatrix}$.
From that, we easily find two eigenvalues: $A \begin{bmatrix}\vec v\\\vec v\end{bmatrix} = \begin{bmatrix}2\vec v\\2\vec v\end{bmatrix}$ and $A \begin{bmatrix}\vec v\\-\vec v\end{bmatrix} = \begin{bmatrix}\vec 0\\\vec 0\end{bmatrix}$.
Each eigenvalue is with multiplicity $2$, as $\vec v$ is a vector of $2$ dimensions.