Your open cover does cover all $]0,1[$.
Let $x \in ]0,1[$ then $0 < x < 1$. Let $n$ be a positive integer so that $n > \frac 1x$. (The integers are not bounded so there will be such an integer-- this is actually one of the consequences of the Archimedean Property; it's something that actually has to be proven but... that's for another post.)
So $n > \frac 1x$ so $0 < \frac 1n < x$. So $x \in ]\frac 1n, 2[$. So all points $x$ in $A$ are covered by your subcover.
And I assume you figured out that now finite subset of this cover successfully covers? (as per Jorge Fernandez Hidalgo's answer shows.)