Write $\alpha_l = w + ia_l$ and apply the substitution $x_l \mapsto -x_l$. Then the identity is equivalent to
$$ \int_{[0,\infty)^n} \prod_{j < l} \left( 1 - 2 k_{jl} \mathbf{1}_{\{x_l > x_j\}} \right) \prod_{l=1}^{n} \alpha_l e^{-\alpha_l x_l} \, dx_l = \prod_{j<l} \left(1 - 2 k_{jl} \frac{\alpha_j}{\alpha_j + \alpha_l} \right). \tag{*}$$
Now consider the case where $n = 3$ and $k_{12} = k_{23} = 1$ but $k_{13} = 0$. Then the LHS of $\text{(*)}$ is
$$ 1 - \frac{2\alpha_1}{\alpha_1 + \alpha_2} - \frac{2\alpha_2}{\alpha_2 + \alpha_3} + \frac{2\alpha_1}{\alpha_1 + \alpha_2 + \alpha_3} \cdot \frac{2\alpha_2}{\alpha_2 + \alpha_3} $$
while the RHS is
$$ 1 - \frac{2\alpha_1}{\alpha_1 + \alpha_2} - \frac{2\alpha_2}{\alpha_2 + \alpha_3} + \frac{2\alpha_1}{\alpha_1 + \alpha_2} \cdot \frac{2\alpha_2}{\alpha_2 + \alpha_3} $$
They cannot equal and hence the identity does not hold.
I suspect that the identity is true exactly when $(k_{jl})$ satisfies sort of transitivity: for any $j < l$,
$$ k_{jl} = 1 \quad \Leftrightarrow \quad k_{jm} = 1 = k_{ml} \quad \text{for all} \quad j < m < l. $$
I am currently trying to prove that this condition implies the identity $\text{(*)}$. This essentially boils down to proving the identity when $k \equiv 1$, but even this does not seem an easy task.