$\newcommand{\bbx}[1]{\,\bbox[15px,border:1px groove navy]{\displaystyle{#1}}\,}
\newcommand{\braces}[1]{\left\lbrace\,{#1}\,\right\rbrace}
\newcommand{\bracks}[1]{\left\lbrack\,{#1}\,\right\rbrack}
\newcommand{\dd}{\mathrm{d}}
\newcommand{\ds}[1]{\displaystyle{#1}}
\newcommand{\expo}[1]{\,\mathrm{e}^{#1}\,}
\newcommand{\ic}{\mathrm{i}}
\newcommand{\mc}[1]{\mathcal{#1}}
\newcommand{\mrm}[1]{\mathrm{#1}}
\newcommand{\pars}[1]{\left(\,{#1}\,\right)}
\newcommand{\partiald}[3][]{\frac{\partial^{#1} #2}{\partial #3^{#1}}}
\newcommand{\root}[2][]{\,\sqrt[#1]{\,{#2}\,}\,}
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\begin{align}
&\int_{0}^{\infty}
{2\bracks{x - \tanh\pars{x}} \over \sinh\pars{x}\tanh^{2}\pars{x}}\,\dd x
=
\int_{0}^{\infty}\bracks{%
{2x\cosh^{2}\pars{x} \over \sinh^{3}\pars{x}} - {2 \over x^{2}}}\,\dd x\ +\ 2\
\overbrace{\int_{0}^{\infty}\bracks{%
{1 \over x^{2}} - {\cosh\pars{x} \over \sinh^{2}\pars{x}}}\,\dd x}^{\ds{=\ 0}}
\end{align}
The second integral is trivially evaluated. Indeed,
@Simply Beautiful Art already pointed out in his answer that the second integral involves
$\ds{\dd\bracks{\mrm{csch}\pars{x}}/\dd x = -\cosh\pars{x}/\sinh^{2}\pars{x}}$.
Then,
\begin{align}
&\int_{0}^{\infty}
{2\bracks{x - \tanh\pars{x}} \over \sinh\pars{x}\tanh^{2}\pars{x}}\,\dd x =
\lim_{\epsilon \to 0^{+}}\braces{%
-\int_{x = \epsilon}^{x \to \infty}x\cosh\pars{x}\,
\dd\bracks{1 \over \sinh^{2}\pars{x}}\,\dd x - {2 \over \epsilon}}
\\[5mm] = &\
\lim_{\epsilon \to 0^{+}}\braces{%
{\epsilon\cosh\pars{\epsilon} \over \sinh^{2}\pars{\epsilon}} + \int_{\epsilon}^{\infty}
{1 \over \sinh^{2}\pars{x}}\bracks{\cosh\pars{x} + x\sinh\pars{x}}\,\dd x -
{2 \over \epsilon}}
\\[5mm] = &\
\lim_{\epsilon \to 0^{+}}\bracks{%
{\epsilon\cosh\pars{\epsilon} \over \sinh^{2}\pars{\epsilon}} + {1 \over \sinh\pars{\epsilon}} + \int_{\epsilon}^{\infty}{x \over \sinh\pars{x}}\,\dd x -
{2 \over \epsilon}} =
\int_{0}^{\infty}{x \over \sinh\pars{x}}\,\dd x
\\[5mm] = &\
2\int_{0}^{\infty}{x\expo{-x} \over 1 - \expo{2x}}\,\dd x =
2\sum_{n = 0}^{\infty}\int_{0}^{\infty}x\expo{-\pars{2n + 1}x}\,\dd x =
2\sum_{n = 0}^{\infty}{1 \over \pars{2n + 1}^{2}} =
2\sum_{n = 0}^{\infty}{1 \over n^{2}} -
2\sum_{n = 0}^{\infty}{1 \over \pars{2n}^{2}}
\\[5mm] = &\
{3 \over 2}\sum_{n = 0}^{\infty}{1 \over n^{2}} =
{3 \over 2}\,{\pi^{2} \over 6} = \bbx{\pi^{2} \over 4}
\end{align}