Claim: Any truth-function $\phi$ defined over two or more variables and using $\neg$ and $\leftrightarrow$ only will have an even number of $T$'s and (therefore) an even number of $F$'s in the truth-table.
Proof: Take any such truth-function $\phi$. Since it involves two or more variables, the number of rows in the truth-table is a multiple of 4. By Induction over structure of $\phi$ we'll show that any subformula of $\phi$ will have an even number of $T$'s and $F$'s in the truth-table of $\phi$
Base: Take atomic statement $P$. In the truth-table of $\phi$, exactly half of the times $P$ will be $T$, and the other half it is $F$. So given that the number of rows in the truth-table is a multiple of 4, there are an even number of $T$'s and an even number of $F$'s
Step: Let $\psi$ be a subformula of $\phi$. We need to consider two cases:
Case 1: $\psi = \neg \psi_1$
By inductive hypothesis, $\psi_1$ has an even number of $T$'s and $F$'s in the truth-table. Since all $T$'s become $F$'s and vice versa when negating, that means that $\psi$ has an even number of $T$'s and $F$'s in the truth-table.
Case 2: $\psi = \psi_1 \leftrightarrow \psi_2$
By inductive hypothesis, $\psi_1$ and $\psi_2$ both have an even number of $T$'s and $F$'s in the truth-table.
Now consider what happens when we evaluate $\psi = \psi_1 \leftrightarrow \psi_2$. Let us first consider the $m$ rows where $\psi_1$ is $T$. Of those rows, assume that $\psi_2$ is $T$ in $m_1$ of those and hence $F$ in $m-m_1$ of those. This gives us $m_1$ $T$'s and $m-m_1$ $F$'s for $\psi$. Now consider the $n$ rows where $\psi_1$ is $F$. Of those rows, assume that $\psi_2$ is $T$ in $n_1$ of those and hence $F$ in $n-n_1$ of those. This gives us $n_1$ $F$'s and $n-n_1$ $T$'s for $\psi$. So, in total we get $m_1 + p_2$ $T$'s and $m_2 + p_1$ $F$'s for $\psi$.
But, since by inductive hypothesis $\psi_1$ has an even number of $T$'s, we know $m = m_1 + m_2$ and $n = n_1 + n_2$ are both even and thus $m_1$ and $m_2$ have the same parity, and same for $n_1$ and $n_2$. Also, since by inductive hypothesis $\psi_2$ has an even number of $T$'s and $F$'s in the truth-table, we have that $m_1 + n_1$ and $m_2 + n_2$ are both even, meaning that $m_1$ and $n_1$ have the same parity, and same for $m_2$ and $n_2$. Combining this, that means that $m_1$ and $n_2$ have the same parity, and same for $m_2$ and $n_1$. Hence, $m_1 + p_2$ and $m_2 + p_1$ are both even, meaning that $\psi$ has an even number of $T$'s and $F$'s in the truth-table.
Now that we have proven the claim, we know that you cannot capture truth-functions that have an odd number of $T$'s and an odd number of $F$'s in the truth-table. Hence, $\{ \neg, \leftrightarrow \}$ is not expressively complete.
Finally, let's point out that $P \oplus W \Leftrightarrow \neg P \leftrightarrow Q$. This means that if $\{ \neg, \leftrightarrow, \oplus \}$ is expressively complete, then $\{ \neg, \leftrightarrow \}$ is expressively complete as well. But since we just proved that $\{ \neg, \leftrightarrow \}$ is not expressively complete, it follows that $\{ \neg, \leftrightarrow, \oplus \}$ is not expressively complete either.
Step two: Figure out if your set fulfills this requirement or not. – Dirk Jun 29 '17 at 12:35