Not a solution but a reformulation of the problem.
Your conjecture is actually a weaker form of the famous unsolved Goldbach conjecture. When you state $n^2-k^2=(n-k)(n+k)=pq$ with primes $p$ and $q$, then this means
$$n-k=p,n+k=q\qquad\text{or}\qquad n-k=1,n+k=pq.$$
In the former case this means that $n$ is the average of the two prime numbers $p$ and $q$:
$$\frac{p+q}2=\frac{(n-k)+(n+k)}2=\frac{2n}2=n$$
or that $2n$ is the sum $p+q$. This is exactly the statement of the Goldbach conjecture. However, your conjecture contains the other case $k=n-1$, thus $n+k=2n-1=pq$.
Your weaker version is
Conjecture. Any even number is either the sum of two primes or one more than the product of two primes. Formally, for all $n$ there are primes $p,q$ so that
$$2n=p+q\qquad\text{or}\qquad 2n=pq+1.$$
Even though it is weaker, it might be still a very hard problem.