Let $X=\{x_0, x_1, \ldots\}$ be a countable discrete space.
Take $a_0 = [(x_0, 1)]\in SX$ to be a basepoint (the choice of $x_0$ doesn't matter, they all give the same point in $SX$).
Now for each $i\in\mathbb{N}$ define
$$V_i=\bigg\{(x_i, t)\ \bigg|\ \frac{1}{3} < t \leq 1\bigg\}$$
Note that each $V_i$ is open in $X\times[0,1]$. If we now go to the suspension then we can define
$$U_i=p\big(\{x_i\}\times[0,1]\big)\cup \bigcup_i p\big(V_i\big)$$
where $p:X\times[0,1]\to SX$ is the projection. So it's like a circle with a countable umbrella at the top.
A little bit of gymnastics is needed to show that each $U_i$ is open in $SX$ and is homotopically equivalent to $S^1$. Also any interesection of the form $U_{i_1}\cap\cdots\cap U_{i_n}$ is contractible (as long as there are at least two different $U_i$ there). Every such intersection is an umbrella without full circle, you can contract it to the basepoint.
Thus van Kampen applies and therefore
$$\pi_1(X)\simeq *\pi_1(U_i)\simeq *_i\pi_1(S^1)\simeq *_i\mathbb{Z}$$
On a related note, you should be able to find a homotopy equivalent space (Hawaian earings) whose fundamental group you know.
– Tyrone Jul 10 '17 at 13:58