Here's a foolproof way of finding the argument of a complex number.
First ignore all the signs of the imaginary and real parts. Take the ratio of the absolute values of the imaginary and the real parts and find the arctangent of that. In your case, that would be $\arctan \sqrt 3 = \frac{\pi}{3}$.
This is the reference angle (call it $\alpha$) of the argument, just like in "usual" trigonometry. The reference angle always lies in the first quadrant.
Now decide which quadrant the complex number lies in. Plot it on an Argand diagram (Cartesian plane). In this case, since the real value ($x$ axis) is negative and the imaginary value ($y$ axis) is positive, the number lies in the second quadrant.
For first quadrant, the argument equals the reference angle $\alpha$.
For second quadrant, the argument equals $\pi-\alpha$
For third quadrant, the argument equals $\pi+\alpha$. However, the principal value of the argument (by convention) lies in the interval $(-\pi, \pi]$. The equivalent value is then $\alpha - \pi$, since angles that differ by a multiple of $2\pi$ are equivalent.
For the fourth quadrant, the argument equals $2\pi - \alpha$. Again, to get the argument within the conventional range of the reference value, we take the argument to be simply $-\alpha$.
In your case, the argument would follow the second quadrant case, and that's $\pi - \frac{\pi}{3} = \frac{2\pi}{3}$