By definition, for a number $n$, if there exists some number $k\in\mathbb Z$ such that $n=2\cdot k$, then $n$ is even.
- For $0$, we know that $0=2\cdot 0$
- Therefore, if $k=0$, we know that $0=2\cdot k$,
- Therefore, it is true that there exists some $k\in\mathbb Z$ such that $0=2\cdot k$.
- Therefore, $0$ is even (because the statement "$0$ is even is equivalent to the statement in the point above).
That's all. That's how mathematical definitions work.
There is no part of the definition that says "but if $n=3\cdot k$, then $n$ is not even".
Your point is completely off-topic. So what if $0=3\cdot 0$? Does that have any effect on the truth of the statement $0=2\cdot 0$?
Does the fact that $12=3\cdot 4$ mean that $12$ is not an even number?
What you ar experiencing is pretty normal for people first experiencing mathematical proofs. You must understand that just because something seems "strange", that is no reason for it to be wrong. If you can prove a mathematical statement, then that statement is true, no matter how strange it may sound to you.
The way to prove a statement is by following strict definitions, and only the definitions. In your case, all multiples of $2$ are even, and that's all you know, so that's all you have to work with.