Let me try at explanation that would hopefully work for kids.
Angelo fills three large jugs, but does not have enough to fill a
fourth one.
This sentence can be written as $3L < 50 < 4L$.
You could explain it by expanding on the sentence in a fashion: "Angelo fills three jugs, i.e. there is enough water to fill three large jugs, or 50 litres is more than volume of three large jugs.", or something similar. Also, $4L>50$ because if it would not be, Angelo would be able to fill another large jug.
(Though, not quite, it is actually $3L\leq 50 < 4L$, but that first inequality is strict is implicit in the later text, and also, equality is impossible if integral values are assumed)
With the remaining water he fills three small jugs, but does not have
enough left to fill a fourth.
This gives us $3S \leq 50-3L <4S$.
The explanation is the same as before, with addendum that we now only have the remainder of water after filling large jugs, which is $50-3L$.
(Note that now we cannot exclude equality case in our inequality.)
Now, we have well defined problem in mathematical language. So, all that we have to do now is see how to deal with the system of inequalities
$$3L < 50 < 4L\\3S\leq 50-3L < 4S$$
and it depends on how familiar your students are with these kind of things.
Low level method of solving would be guessing that $13\leq L \leq 16$ since if $L \leq 12$, then $4L\leq 48$, and if $L\geq 17$, then $3L\geq 51$.
But, if your students are familiar with linear inequalities, just solve them to get $$\frac{50}4< L < \frac{50}3.$$
Now, it is basically casework: $L\in\{13,14,15,16\}$. Again, if your students are familiar with solving linear inequalities, first write
$$\frac{50-3L}{4}< S \leq \frac{50-3L}{3}$$ and then the casework becomes:
$1.$ $\frac{11}{4} < S \leq \frac{11}{3}$
$2.$ $\frac{8}{4} < S \leq \frac{8}{3}$
$3.$ $\frac{5}{4} < S \leq \frac{5}{3}$
$4.$ $\frac{2}{4} < S \leq \frac{2}{3}$
with only the first case giving us solution $L = 13$, $S = 3$.
If your students don't know how to solve linear inequalities, then the casework becomes
$1.$ $3S \leq 11 < 4S$
$2.$ $3S \leq 8 < 4S$
$3.$ $3S \leq 5 < 4S$
$4.$ $3S \leq 2 < 4S$
and still it is not too hard to guess the solution.
If your students are familiar with graphing linear functions, you can show them this graph:
