It's well known that $x > \sin x$ for $x> 0$. The Taylor series of $ x - \sin x$ is also well known, and the coefficients are alternating. However, it appears that the Taylor coefficients of the function $\tan x - \tan (\sin x)$ are all positive ( and this implies that $x > \sin x$ on $(0, \pi/2)$, as it should). It's not clear for me why this is true.
In fact, one can go further as follows. It is known that we have inequalities of the form $$\sum_{k=0}^{2 l} (-1)^k\frac{x^{2k+1}}{(2k+1)!}< \sin x < \sum_{k=0}^{2 m + 1}(-1)^k \frac{x^{2k+1}}{(2k+1)!}$$ for $x > 0$.
Let's consider for instance the inequality $$x< \sin x + \frac{x^3}{6}$$ for $x>0$. Now, it appears again that the function $\tan ( \sin x + x^3/6) - \tan x$ has a "positive" Taylor expansion.
Similarly for $\tan ( x + \frac{x^5}{120}) - \tan( \sin x + x^3/6)$, and so on, for any inequality with positive coefficients obtained from the above by switching sides of terms.
One can substitute the function $\sec$ for the function $\tan$.
I am aware of the Taylor expansions of the functions $\tan$ and $\sec$ ( see the wikipedia article on trigonometric functions), they are all positive, and have a combinatorial interpretation.
One can do some testing with WolframAlpha or any computer algebra system.