Reducing the problem to compare crust length of square (sq) vs circle (cl) pizza.
Since both pizzas use the same amount of dough and have to be the same thickness, the surface area of both pizzas will be the same. (In fact, the surface area of any pizza shape - even irregular - rolled out from the same amount of dough to the same thickness will be the same.)
So, $S_(sq)=S_(cl)$ ⇒
$$a^2 = \pi r^2$$
$$\frac{a}{r}=\sqrt\pi = 1.77$$
Now, if the perimeter crust of the square pizza (P) is longer than the circumference of the circle pizza (C), $\frac{P}{C} > 1$.
$P = 4a$ and $C = 2\pi r$
$$\frac{P}{C} = \frac{4a}{2\pi r} = $$
$$= \frac{2}{\pi} * \frac{a}{r} = 0.637 * 1.77=1.13$$
So, $\frac{P}{C} >1 $, which means you get more crust from a square pizza.