The diagonals of a square intersect at right angles and bisect the angles at the vertices. Therefore, the direction vectors of the sides are angle bisectors of the diagonals (and so also angle bisectors of their normals).
We’re given that one diagonal lies on the line $2x+3y=5$. A normal vector to this line can be read directly from the equation: $\mathbf n_1=(2,3)$, and from this we get a normal to the other diagonal, $\mathbf n_2=(3,-2)$. These two vectors have the same length, so their angle bisectors are simply their sum and product. Using the point-normal form of the equation for a line, this gives $$[(3,-2)+(2,3)]\cdot(x,y)-[(3,-2)+(2,3)]\cdot(-1,3)= 5x+y-2=0$$ and $$[(3,-2)-(2,3)]\cdot(x,y)-[(3,-2)-(2,3)]\cdot(-1,3)=x-5y-16=0$$ for equations of the lines on which the sides of the square that meet at the vertex $(1,-3)$ lie.