You can use Gauss test (or Rabee's test, the latter is weaker but still suffices), I will use the Gauss test:
If $u_n >0$ and satisfies
$$\frac{u_n}{u_{n+1}} = 1 + \frac{h}{n} + O(\frac{1}{n^r})$$ for some $r>1$, then $\sum u_n$ converges iff $h>1$.
In your case, $$u_n = \frac{1\cdot 3\cdots (2n-3)}{2^n n!} = \frac{(2n-2)!}{2^{2n-1}n!(n-1)!}$$ we easily obtain
$$\frac{u_n}{u_{n+1}} = \frac{2n+2}{2n-1} = 1+\frac{3}{2n-1} = 1+\frac{3}{2n}+O(\frac{1}{n^2})$$
so $\sum u_n$ converges.
Alternatively, you can use the Stirling formula
$$n! \sim \sqrt{2\pi n}(\frac{n}{e})^n$$ but I think this is an overkill.
The value of the sum can be derived from the following series (after integrating and shifting terms):
$$\sum_{n=0}^\infty \binom{2n}{n}x^n = \frac{1}{\sqrt{1-4x}}$$