It is indeed permutation. It is $1 *$ $ _{(X-1)}$$P$$_5$, for X=amount of people in the class. The first one with the request is not counted (because he goes first. Period. We only have the schedule the remaining five), so that's why we only have to pick the remaining five, and have the choice of $X-1$ (We don't want the first one two times, right?). This should answer your question.
EDT:
Yes, $1 * 5!$ is the right answer for $X = 6$ (which I think is the case, by re-reading your question), because
$$_{6 - 1}P_5 = _5P_5 = \frac{5!}{(5-5)!} = \frac{5!}{0!} = \frac{5!}{1} = 5! = 120$$
So yeah, that's the right answer.