Hyperbolic manifolds have constant sectional curvature $-1$. The two-holed torus, for example, can (I believe) be given a hyperbolic metric so that it has curvature $-1$. It should also be a complete metric space, with this metric.
It would seem as though this should make the two-holed torus with this metric a CAT(0) space (even a CAT(-1) space). However, the two-holed torus is obviously not contractible, but CAT(0) spaces are contractible.
I'm sure I'm just confused about the definitions, but I'm not sure where.