An arbitrage opportunity exists if an asset price $V_t$ (considered as a stochastic process on a filtered probability space) satisfies at present time $0$ and future time $T$
$$V_0 = 0, \quad P(V_T \geqslant 0) = 1, \quad P(V_T \neq 0) > 0.$$
In other words, we could buy the asset for nothing and the future value is almost surely nonnegative with a non-zero probability of a positive value.
In the absence of arbitrage, there exists a probability measure $Q$ called the risk-neutral measure such that the price of an asset $V_t$ at any time $0 \leqslant t \leqslant T$ can be obtained as an expected value. In particular, it is the expectation of the future price under conditioned on all information known at time $t$ and discounted at the risk-free rate $r$:
$$V_t \,= \,e^{-r(T-t)}\,\,E^{Q}(V_T \,| \,\mathcal{F}_t).$$
Turning to a call option, the future value or payoff at expiration time $T$ is given in terms of an underlying asset (for example, a stock price). At expiry, the holder of the call option receives the underlying asset with price $S_T$ in exchange for the payment of the strike price $K$ so the value of the option at expiry should be $C_T = \max(S_T- K,0)$. The maximum appears here because a rational holder would not choose to exercise if the value of the asset were less than the strike price. Furthermore, in practice, many options do not require a physical exchange but are, rather, settled in cash.
Since a stock price cannot have a value below zero (shareholders have limited liability) the value of the call option at time $t$ can be expressed as
$$C_t = e^{-r(T-t)} \int_0^\infty \max(S_T-K,0) f(S_T |S_t)\, dS_T \\= e^{-r(T-t)} \int_K^\infty (S_T-K) f(S_T|S_t) \, dS_T$$
where $f(S_T|S_t)$ is the conditional probability density of the future stock price $S_T$ (given the current known price $S_t$).
The usual starting point for option pricing is to assume that, under the risk-neutral measure, $S_t$ follows a stochastic process of the form
$$\frac{dS_t}{S_t} = r \, dt + \sigma \, dZ_t$$
where $Z_t$ is a Brownian motion and the parameter $\sigma$ is called the volatility. In this case, the probability density $f$ will be a normal PDF and a closed-form solution can be found depending on the parameters already discussed:
$$C_t = C(t; T,S_t,K,r, \sigma) = \text{Black-Scholes formula}$$
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