A hint: Define the length $L(c)$ of every piecewise-linear path $c$ to be its Euclidean length. Define the length $L(c)$ to be $\infty$ for all other continuous paths $c$. Now, go through the list of axioms of a length structure (see e.g.here) that this is indeed a length structure. Lastly, think of a path $c$ such that $L(c)$ differs from the Euclidean length of $c$.
Edit. Suppose, in addition to the usual axioms of a length space you want the set of paths of finite length to be the same as in the Euclidean case. Here is a modification of my construction above:
Let $A$ be the subset of rectifiable (from Eucldiean viewpoint) continuous curves (maps from finite intervals to $R^2$). Let's define a length structure on $A$ as follows. For each $f:[a,b]\to R^2$ which belongs to $A$, let $S_f\subset [a,b]$ be the union of all open intervals $I\subset [a,b]$ such that $f$ restricted to these intervals is smooth (say, $C^1$). Then the Euclidean length $L(f)$ of $f$ equals
$$
L(f)=\int_{S_f}|f'(t)|dt + R_f.
$$
Furthermore, let $G_f$ be the union of all open subintervals of $S_f$ such that the restriction of $f$ to each of these subintervals is linear (more precisely, affine). Lastly, let $H_f:= S_f - G_f$. Now, set
$$
L'(f):= \int_{G_f}|f'(t)|dt + 2\int_{H_f}|f'(t)|dt + R_f.
$$
Hence, for each piecewise-linear path $f$, $L'(f)=L(f)$ but, in general, $L'(f)\ne L(f)$. For each nonrectifiable path $f$ set $L'(f)=\infty$.
I will leave you to check that $L'$ satisfies all the axioms of a length structure and defines the usual (Euclidean) distance on $R^2$ (since we did not change lengths of linear paths).