As Adrian Keister already answered, you need to solve the equation
$$\beta=\alpha-\sin(\alpha)\qquad \text{where}\qquad \beta=\frac{8A}{d^2}$$ and a numerical method (Newton method will be the simplest) will be required.
However, approximations could be done. For example, if $\beta$ is small, Taylor series built around $\alpha=0$ would give
$$\beta=\frac{\alpha ^3}{6}-\frac{\alpha ^5}{120}+\frac{\alpha ^7}{5040}-\frac{\alpha
^9}{362880}+O\left(\alpha ^{11}\right)$$ and using series reversion
$$\alpha=\sqrt[3]{6} \beta ^{1/3}+\frac{ 1}{10}\beta+\frac{3\ 3^{2/3} }{350
\sqrt[3]{2}}\beta ^{5/3}+\frac{\sqrt[3]{3} }{350\ 2^{2/3}}\beta ^{7/3}+O\left(\beta
^3\right)$$
For illustration purposes,
$$\left(
\begin{array}{ccc}
\beta & \text{approximation} & \text{exact} \\
0.00 & 0.00000 & 0.00000 \\
0.25 & 1.17122 & 1.17123 \\
0.50 & 1.49722 & 1.49730 \\
0.75 & 1.73605 & 1.73633 \\
1.00 & 1.93387 & 1.93456 \\
1.25 & 2.10733 & 2.10876 \\
1.50 & 2.26458 & 2.26717 \\
1.75 & 2.41030 & 2.41461 \\
2.00 & 2.54744 & 2.55420 \\
2.25 & 2.67799 & 2.68810 \\
2.50 & 2.80340 & 2.81799 \\
2.75 & 2.92471 & 2.94517 \\
3.00 & 3.04274 & 3.07077
\end{array}
\right)$$ which seems to be quite reasonable.
Edit
We can make the approximation looking nicer using $\beta=\frac{\gamma ^3}{6}$ (or $\gamma=\sqrt[3]{6\beta}$) and get
$$\alpha=\gamma +\frac{\gamma ^3}{60}+\frac{\gamma ^5}{1400}+\frac{\gamma
^7}{25200}+\cdots$$
We could even make the approximation better continuing the expansion and transforming the result as a Padé approximant to get
$$\alpha=\gamma\, \frac{1-\frac{1493 }{21120}\gamma^2+\frac{167 }{268800}\gamma^4} { 1-\frac{123 }{1408}\gamma^2+\frac{403 }{295680}\gamma^4}$$ leading to
$$\left(
\begin{array}{ccc}
\beta & \text{approximation} & \text{exact} \\
0.00 & 0.00000 & 0.00000 \\
0.25 & 1.17123 & 1.17123 \\
0.50 & 1.49730 & 1.49730 \\
0.75 & 1.73633 & 1.73633 \\
1.00 & 1.93456 & 1.93456 \\
1.25 & 2.10874 & 2.10876 \\
1.50 & 2.26713 & 2.26717 \\
1.75 & 2.41452 & 2.41461 \\
2.00 & 2.55403 & 2.55420 \\
2.25 & 2.68780 & 2.68810 \\
2.50 & 2.81747 & 2.81799 \\
2.75 & 2.94431 & 2.94517 \\
3.00 & 3.06939 & 3.07077
\end{array}
\right)$$