In general, the answer might depend on whether this is considered to be the integral over a region in $\mathbb{R}^2$ with respect to the product measure,
$$\tag{1}I = \int_D (x+y)^{-\alpha}$$
or as iterated integrals
$$\tag{2} J= \int_0^1 \left(\int_0^{1-x} (x+y)^{-\alpha} \, dy \right) \, dx $$
In this case it doesn't matter, but I will answer with reference to (1).
The diagonal boundary of the region of integration falls in between circular arcs with radii $1/2$ and $1$.
Since the integrand is nonnegative,
$$\int_0^{\pi/2}\int_0^{1/2} \frac{r \, dr \, d\theta}{r^\alpha(\cos \theta + \sin \theta)^\alpha} \leqslant I \leqslant \int_0^{\pi/2}\int_0^{1} \frac{r \, dr \, d\theta}{r^\alpha(\cos \theta + \sin \theta)^\alpha}$$
Note that $\cos \theta + \sin \theta > 0$ for $\theta \in [0,\pi/2]$ which implies that
$$\int_0^{\pi/2} \frac{d \theta }{(\cos \theta + \sin \theta)^{\alpha}},$$
converges for all $\alpha$.
Thus, we have convergence of $I$ if $\alpha < 2$ and divergence if $\alpha \geqslant 2$, determined by the convergence/divergence of
$$\int_0^c \frac{dr}{r^{\alpha-1}}$$.