Here's an approach that at least reduces the problem to solving a quartic polynomial.
Let $x=3u$ and $\phi=\theta+u$, so that the equation becomes $3\sin3\phi=2.5/\sin(\phi-u)$, or
$$6\sin3\phi(\sin\phi\cos u-\cos\phi\sin u)=5$$
If you can solve this for $\phi$ in terms of $u$, you can easily convert that solution to one for $\theta$ in terms of $x$.
Now $\sin3\phi=3\sin\phi-4\sin^3\phi$, hence, letting $s=\sin\phi$, we have
$$6(3s-4s^3)\left(s\cos u-\sqrt{1-s^2}\sin u\right)=5$$
or
$$6(3-4s^2)s^2\cos u-5=6(3-4s^2)\sqrt{s^2-s^4}\sin u$$
Squaring both sides produces a quartic polynomial in $s^2$, with coefficients that can be expressed in terms of $\cos u$ (since $\sin^2u=1-\cos^2u$). I.e., letting $S=s^2=\sin^2\phi$ and $C=\cos u=\cos(x/3)$, we have
$$(6C(3-4S)S-5)^2=36(1-C^2)(3-4S)^2(S-S^2)$$
which expands out to a quartic in $S$. Because it's a quartic, this can, in principle, be solved for $S=s^2$, after which you can pick out solutions (if any) to the non-squared equation, but unless a miracle occurs (or there's a simplification I don't see), it looks like a mess. This leads me to wonder where this problem came from; it certainly doesn't strike me as a routine homework exercise.