For $n$ even, say $2m$, we can write
$$\begin{align}
\int_0^{\pi/2}\frac{\sin(2mx)}{\sin(x)}\,dx&=\text{Im}\int_0^{\pi/2}\frac{e^{i2mx}}{\sin(x)}\,dx\\\\
&=2\text{Re}\int_0^{\pi/2}\frac{e^{i2mx}}{e^{ix}-e^{-ix}}\,dx\tag1
\end{align}$$
Then, letting $z=e^{ix}$ and using long division reveals that
$$\begin{align}
\text{Re}\left(\frac{e^{i2mx}}{e^{ix}-e^{-ix}}\right)&=\text{Re}\left(\frac{z^{2m+1}}{z^2-1}\right)\\\\
&=\text{Re}\left(\sum_{k=1}^{m}z^{2k-1}+\frac{1}{z-1/z}\right)\\\\
&=\sum_{k=1}^{m} \cos((2k-1)x)\tag 2
\end{align}$$
Then, substituting $(2)$ into $(1)$ we find that
$$\int_0^{\pi/2}\frac{\sin(2mx)}{\sin(x)}\,dx=2\sum_{k=1}^{m} \frac{(-1)^{k-1}}{2k-1}$$
If $n=2m+1$, then we see that
$$\begin{align}
\int_0^{\pi/2}\frac{\sin((2m+1)x)}{\sin(x)}\,dx&=\text{Im}\int_0^{\pi/2}\frac{e^{i(2m+1)x}}{\sin(x)}\,dx\\\\
&=2\text{Re}\int_0^{\pi/2}\frac{e^{i(2m+1)x}}{e^{ix}-e^{-ix}}\,dx\tag1
\end{align}$$
Then, letting $z=e^{ix}$ and using long division reveals that
$$\begin{align}
\text{Re}\left(\frac{e^{i(2m+1)x}}{e^{ix}-e^{-ix}}\right)&=\text{Re}\left(\frac{z^{2m+2}}{z^2-1}\right)\\\\
&=\text{Re}\left(\sum_{k=0}^{m}z^{2k}+\frac{1/z}{z-1/z}\right)\\\\
&=\frac12+\sum_{k=1}^{m} \cos(2kx)\tag 2
\end{align}$$
Then, substituting $(2)$ into $(1)$ we find that
$$\int_0^{\pi/2}\frac{\sin(2mx)}{\sin(x)}\,dx=\frac{\pi}{2}$$