If $A$ is symmetric then $A^{-1}$ is also symmetric so you reduced the third option to the second. Namely, for every even $p \in \mathbb{N}$ we have that $A^{-p}$ is positive.
For the fourth option, since $A$ is symmetric there exists an orthogonal matrix $U$ and a diagonal matrix $D$ such that $$A = U^TDU$$
Now we have
$$e^{pA} = e^{pU^TDU} = U^Te^{pD}U$$
Namely, if $D = \pmatrix{\lambda_1 & 0 &\cdots &0 \\
0 & \lambda_2 & \cdots & 0\\
\vdots & \vdots & \ddots & \cdots \\
0 & 0 & \cdots &\lambda_n}$ then $e^{pD} = \pmatrix{e^{p\lambda_1} & 0 &\cdots &0 \\
0 & e^{p\lambda_2} & \cdots & 0\\
\vdots & \vdots & \ddots & \cdots \\
0 & 0 & \cdots &e^{p\lambda_n}}$.
So $e^{pA}$ is also symmetric and with real eigenvalues $e^{p\lambda}$ where $\lambda \in \sigma(A)$.
Now $e^{pA} - I$ has eigenvalues $e^{p\lambda} - 1$.
If we take an example like $$A = \pmatrix{1 & 0 \\ 0 & -1} \implies e^{pA} - I = \pmatrix{e^p-1 & 0 \\ 0 & e^{-p}-1}$$
there is no way both $e^p-1$ and $e^{-p}-1$ can be positive so option $4$ is false.