Thanks for all the replies. I myself finally got a solution, the proof is as follows:
Since $A$ positive definite, $A$ can be uniquely factorized as $A=U^{\top}U$, where $U$ is an upper triangular matrix.
Because $||b||$ is finite, and $||a|| \to \infty$, then $A\frac{a}{||a||}=\frac{b}{||a||} \to 0$ (this part was inspired by coppert.hat's post, much appreciate that), then $\left(\frac{a}{||a||}\right)^{\top}A\left(\frac{a}{||a||}\right) \to 0$, then $\left(U\frac{a}{||a||}\right)^{\top}\left(U\frac{a}{||a||}\right) \to 0$.
For simplicity, assume that $a$ has only its $i$-th entry $a_i\to \infty$, and the other entries are finite. Set $||a||=||a||_{\infty}=|a_i|$, then $\frac{a}{||a||}$ is a vector with its $i$-th entry be 1, and all other entries be $\to 0$.
Since the sizes of $U$ and $\frac{a}{||a||}$ are all finite, $U\frac{a}{||a||} \to U_i$, where $U_i$ is the $i$-th column of $U$. Then $\left(U\frac{a}{||a||}\right)^{\top}\left(U\frac{a}{||a||}\right) \to 0 \Rightarrow U_i^{\top}U_i \to 0 \Rightarrow U_i \to 0 \Rightarrow U_{ii} \to 0$.
{Because $U$ is upper triangular, det$U$=$\sum_{j=1}^{n} U_{jj} \to 0$ due to that $U_{ii}\to 0$ and $n$ finite.
Note: This part is not rigorous, we also need the other diagonal elements $U_{jj} (j\neq i)$ be bounded to support the conclusion. The modification will be made in the following.
}
Because $A$ positive definite, a basic Cholesky decomposition step can be made as follows:
$$
A= \left[
\begin{matrix}
A_{11} & v^{\top}\\
v & B\\
\end{matrix} \right]
= \left[ \begin{matrix}
\sqrt{A_{11}} & 0^{\top}\\
\frac{v}{\sqrt{A_{11}}} & I_{n-1}\\
\end{matrix} \right]
\left[ \begin{matrix}
1 & 0^{\top}\\
0 & B-\frac{vv^{\top}}{A_{11}}\\
\end{matrix} \right]
\left[ \begin{matrix}
\sqrt{A_{11}} & \frac{v^{\top}}{\sqrt{A_{11}}}\\
0 & I_{n-1}\\
\end{matrix} \right]
$$
- $U_{11}=\sqrt{A_{11}}$ is bounded because all entries in $A$ is bounded .
- Denote $B'=B-\frac{vv^{\top}}{A_{11}}$, then $B'_{11}$ is nonzero and bounded. It is nonzero because $B'$ must be positive definite; it is bounded because $B'_{11}=B_{11}-v_1^2/A_{11}$, all the values on the right hand side are finite, and $A_{11} \neq 0$. As a result, $U_{22}=\sqrt{B'_{11}}$ is nonzero and finite.
- By induction, if the matrix size $n$ is finite, then all the diagonal entries of $U$ are nonzero and finite.
Now because $U$ is upper triangular, det$U$=$\sum_{j=1}^{n} U_{jj} \to 0$, due to that 1) $U_{ii}\to 0$; 2) $U_{jj} (j\neq i) $ finite; 3) $n$ finite.
Finally, det$A$=(det$U$)$^2 \to 0$.
If $a$ has more than one entries that have very large magnitude, e.g. $\left\{ a_{i1}, a_{i2}, \cdots, a_{il} \right\} \to \infty$. Follow the above procedure, we can still prove that $U_{il,il}\to 0$, then $\det (U) \to 0$.
ps. Here the notation $\to 0$ only means that the value has a very small magnitude.