You are right.
A simple random sample is a subset of the population chosen so that each member of the population has the same probability of being in the sample. It is clearly stated that the population here is the set of American families, while it seems that the sample was chosen from Alaskan families. If this is the case, then for any American family that isn't Alaskan, the chance of them being in the sample is 0, while for a family which was picked, the chance was (obviously) nonzero. Thus, it would not be a simple random sample.
However, if the statement that they were chosen randomly means that everyone had an equal chance of being in the sample, but it happened to be the case that all 100 families chosen were Alaskan, then it would in fact be a simple random sample.
A simple random sample is not inherently biased (if everyone has the same chance of being in the sample, how could it be?). However, it is simply a method of choosing who will be in the sample, and not how the sample itself is taken. Is it an optional anonymous survey? Are they asked in public, in front of friends and/or family? For this reason, being a simple random sample does not guarantee that it is an unbiased sample.
Lastly, this should be a lesson as to the downsides of SRS. However unlikely, there is always the possibility of a fluke like this, where everyone or most people in the sample have some similar trait which could be a lurking variable for the parameter being studied. If we suspect that different subsets of the population will have different answers inherent to their age, sex, location, race, religion, ethnicity, etc, then we would be better off using a sampling scheme which dealt with each group separately. Otherwise, we could simply increase the sample size to a significant multiple of the number of groups to increase the chances of each group having some representation in the sample.
Statistics is not an exact science, and nothing gained from a statistical study or experiment is ever "fact". We determine the validity in the context of the problem we are trying to solve and the probability of getting such a sample. Sometime, we just get extremely rare samples, and blindly calling them valid simply because they pass some mathematical test with arbitrary requirements is missing the point entirely.